SWL-Mathematics and Natural Sciences
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Browsing SWL-Mathematics and Natural Sciences by Subject "Activated carbon monoliths"
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Item Effect of carbonization temperature on the physical and electrochemical properties of supercapacitor electrode from fibers of oil palm empty fruit bunches(2015-09-07) Ishak; Deraman, Mohamad; Talib; Basri, Nur Hamizah; Awitdrus; Farma, Rakhmawati; Taer, Erman; Omar, Ramli; Dollah, Besek Nurdiana MohdSelf-adhesive carbon grains (SACG) was prepared from fibers of oil palm empty fruit bunches. The SACG green monoliths were carbonized in N2 environment at 400, 500, 600 and 700°C to produce carbon monoliths labeled as CM1, CM2, CM3 and CM4 respectively. The CMs were activated in CO2 surrounding at 800°C for 1 hour to produce activated carbon monolith electrodes (ACM1, ACM2, ACM3 and ACM4). The physical properties of the CMs and ACMs were investigated using X-ray diffraction, field emission scanning electron microscopy (FESEM) and N2 adsorption-desorption isotherm techniques. ACMs were used as electrode to fabricate symmetry supercapacitor cells and the cells’ performances were investigated using electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV) and galvanostatic charge-discharge (GCD) standard techniques. In this paper we report the physical and electrochemical properties of the ACM electrodes by analyzing the influence of the carbonization temperature on these propertiesItem Physical and electrochemical properties of supercapacitor composite electrodes prepared from biomass carbon and carbon from green petroleum coke(2015-09-09) Awitdrus; Deraman, Mohamad; Talib; Farma, Rakhmawati; Omar, Ramli; Ishak; Taer, Erman; Dollah, Besek Nurdiana Mohd; Basri, Nur Hamizah; Nor, Najah Syahirah MohdThe green monoliths (GMs) were prepared from the mixtures of pre-carbonized fibers of oil palm empty fruit bunches (or self-adhesive carbon grains (SACG)) and green petroleum coke (GPC) with the mixing ratio of 0, 10, 30, 50 and 70 % GPC, respectively. The GMs were carbonized in N2 environment at 800oC to produce carbon monoliths (CM00, CM10, CM30, CM50 and CM70). The CMs were CO2 activated at 800oC for 1 hour to produced activated carbon monolith electrodes (ACM00, ACM10, ACM30, ACM50 and ACM70). For each percentage of GPC, three duplicate symmetrical supercapacitor cells were fabricated using these activated carbon monolith electrodes respectively, and the capacitive performance amongst the cells was compared and analyzed in order to observe the relationship between the capacitive performance and the physical properties (microstructure and porosity) of the ACMs electrodes containing varying percentage of GPC.