KARAKTERISASI DAN KAPASITAS BIOSORPSI BUAH JABON PUTIH (Anthocephalus cadamba Miq.) PADA PENJERAPAN ION TIMBAL(II)

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dc.contributor.authorUbaidah, Abu
dc.contributor.supervisorHanifah, Tengku Abu
dc.date.accessioned2024-02-23T07:31:10Z
dc.date.available2024-02-23T07:31:10Z
dc.date.issued2023-11
dc.description.abstractWhite jabon fruit (Anthocephalus cadamba Miq.) soaked in peat water which is rich in humic acid has the potential to be used as a biosorbent to adsorb lead(II) metal based on the cellulose content of jabon fruit and the active compounds contained in both. This research aims to determine the adsorption capacity and efficiency of white jabon fruit biosorbent in a batch system against lead(II) ions under optimum conditions as well as the appropriate adsorption kinetics and adsorption isotherm models. The optimum biosorbent conditions were determined by optimizing pH (4, 6, 8 and 10), contact time (20, 30, 40 and 50 minutes) and adsorbate concentration (80, 100, 120 and 140 mg/L). The surface morphology of the biosorbent before and after activation with NaOH (1:1, 1:2, 1:3, 1:4 and 1:5 w/w) was analyzed using SEM-EDS, while the functional groups of the biosorbent before and after the biosorption process were analyzed using FTIR. Determination of adsorption capacity and efficiency was analyzed using AAS. The results of the characterization of biosorbents in adsorbing iodine and methylene blue based on SNI 06-3730-1995 show that the best ratio of biosorbent: NaOH activator to activate biosorbents is a ratio of 1:3 (w/w). SEM-EDS results show that the biosorbent before activation contains the elements C, O, Na, Mg, Si, Pb, Cl, K, Ca and Cr while activation only includes the elements C, O, Na and Cl. Optimum conditions occurred at pH 6, contact time 40 minutes and adsorbate concentration 140 mg/L with adsorption capacity and efficiency respectively 6.6385 mg/g and 99.977%. The kinetic model of the biosorbent adsorption process follows pseudo second order kinetics with a rate constant of 0.00235 g/mg min (R2=0.9867) which indicates that the adsorption process involves a chemisorption mechanism. The adsorption isotherm model follows the Freundlich isotherm equation (R2=0.9862) which indicates that adsorption occurs on a heterogeneous surface.en_US
dc.description.sponsorshipFakultas Matematika dan Ilmu Pengetahuan Alamen_US
dc.identifier.citationPerpustakaanen_US
dc.identifier.otherElfitra
dc.identifier.urihttps://repository.unri.ac.id/handle/123456789/11314
dc.language.isoenen_US
dc.publisherElfitraen_US
dc.subjectbiosorbenten_US
dc.subjectlead(II)en_US
dc.subjectwhite jabonen_US
dc.titleKARAKTERISASI DAN KAPASITAS BIOSORPSI BUAH JABON PUTIH (Anthocephalus cadamba Miq.) PADA PENJERAPAN ION TIMBAL(II)en_US
dc.title.alternativeElfitraen_US
dc.typeArticleen_US

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